@article {1111,
	title = {Efficient synthesis of alkynylsilyl ethers and silaketals via base-induced alkynylsilane alcoholysis.},
	journal = {The Journal of Organic Chemistry},
	volume = {69},
	year = {2004},
	month = {2004 Dec 10},
	pages = {8967-70},
	abstract = {<p>The efficient silylation of alcohols with di- and trialkynylsilanes was achieved under base-catalyzed conditions to afford alkynyl silyl ethers and symmetrical alkynyl silaketals in good yield. A selective alcoholysis of dialkynyl silyl ethers to mixed silaketals was also demonstrated. These products served as substrates for enyne ring-closing metathesis and, consequently, as precursors to stereochemically defined 1,3-dienes.</p>
},
	keywords = {Alcohols, Alkalies, Catalysis, Ethers, Molecular Structure, Organometallic Compounds, Silanes},
	issn = {0022-3263},
	doi = {10.1021/jo048908l},
	author = {Grimm, Jonathan B and Lee, Daesung}
}
